Sadow Group Publications are also available at the Iowa State Digital Repository, including open-access manuscripts.
2026
120. Wang, Y.-Y.; Cui, R.; Kim, C. A.; Meng, C.; Bello, M.; Fetters, E. L.; Waltz, E. G.; Qi, L.; Heyden, A.; Peters, B.; et al. A Semi-Flow Reactor Design Diverts Catalytic Hydrogenolysis of Polyolefins to Metastable Kinetic Products. Appl. Catal. B Environ. Energy 2026, 388, 126558. DOI: 10.1016/j.apcatb.2026.126558
119. Byron, C.; McCullough, K.; Hall, J. N.; Ammal, S. C.; Heyden, A.; Bryant, J.; Wang, Y.-Y.; Tonk, K.; Wen, J.; Kropf, A. J.; et al. Data-Driven Discovery of Bimetallic Nanoparticles Catalysts for the Hydrogenolysis of Polyethylene. ACS Catal. 2026, 16, 431-445. DOI: 10.1021/acscatal.5c06514
2025
118. Banerjee, S.; Rodriguez, J.; Mais, M.; Perras, F. A.; Sadow, A. D. Surface Protected Organozirconium Catalyzes C–H Alumination of Saturated Hydrocarbons. Angew. Chem. Int. Ed. 2025, e202511893. DOI: 10.1002/anie.202511893
117. Perras, F. A.; Jena, R.; Sultana, S.; Rahman, M. M.; Sun, S.; Banerjee, S.; Southern, S. A.; Sadow, A. D.; Huang, W.; Odom, A. L. Ultra-Confined Environments May Restrict the Possible Configurations of Supported Metal Complexes. Inorg. Chem. 2025, 64, 14577-14585. DOI: 10.1021/acs.inorgchem.5c02067
116. Li, Y.; Kobayashi, T.; Meira, D. M.; An, L.; Qi, L.; Sadow, A. D. Trimethylaluminum Activates Zeolite-Confined Lanthanum Borohydrides to Enhance Catalytic C–H Borylation. J. Am. Chem. Soc. 2025, 147, 12574-12586. DOI: 10.1021/jacs.4c18569
115. Chen, Z.; Kim, C. A.; Wang, Y.-Y.; Sadow, A. D.; LaPointe, A. M.; Peters, B. Polymer Molecular Weight Distributions: A Tutorial on Transformations between Number Density, Mass Density, and Linear/Logarithmic Axes. Ind. Eng. Chem. Res. 2025, 64, 3695-3703. DOI: 10.1021/acs.iecr.4c04233
114. Lamahewage, S. N. S.; Li, Y.; Sadow, A. D.; Rossini, A. J. Indirect detection of wideline magic angle spinning solid-state NMR spectra of spin-5/2, −7/2, and −9/2 half-integer quadrupolar nuclei. Solid State Nucl. Magn. Reson. 2025, 139, 102032. DOI: 10.1016/j.ssnmr.2025.102032
2024
113. Zhang, Y.; Qi, L.; Li, Y.; Yang, T.; Meira, D. M.; Dun, C.; Hu, H.; Chen, H.; Xu, S.; Urban, J. J.; Sadow, A. D.; Kobayashi, T.; Qi, L.; Tian, P.; Bell, A. T. "Mechanism and Kinetics of Ethanol–Acetaldehyde Conversion to 1,3-Butadiene over Isolated Lewis Acid La Sites in Silanol Nests in Dealuminated Beta Zeolite" ACS Catal. 2024, 14, 15204-15220. DOI: 10.1021/acscatal.4c03935
112. Southern, S. A.; Thompson, A.; Sadow, A. D.; Perras, F. A. "Size matters: altering the metal-surface coordination in micropores via structural confinement effects" Inorg. Chem. Front. 2024, 11, 6862-6873. DOI: 10.1039/D4QI01261E
111. Southern, Scott; Li, Yuting; Sadow, Aaron D.; Qi, Long; Perras, Frederic A. "Enhanced Activity from Coordinatively Unsaturated and Dynamic Zeolite-Bound Organoscandium Species" ACS Catal. 2024, 14, 9440-9451. DOI: 10.1021/acscatal.4c00678
110. Chen, Ziqiu; Sadow, Aaron; Peters, Baron "A microkinetic model for isomerizing ethenolysis" ACS Catal. 2024, 14, 6339-6348. DOI: 10.1021/acscatal.4c00465
109. Wendy Shaw, Tom Autrey, Simon Bare, Elizabeth Biddinger, Shannon Boettcher, Phillip Britt, Robert Brown, R. Morris Bullock, Jingguang Chen, Claus Daniel, Massimiliano Delferro, Peter Dorhout, Kelly Gaffney, Laura Gagliardi, Aaron Harper, David Heldebrant, Michelle Kidder, Oana Luca, Maxim Lyubovsky, Jonathan Male, Daniel Miller, James Morris, Tanya Prozorov, Robert Rallo, Robert Rioux, Aaron Sadow, Joshua Schaidle, Lisa Schulte, Sanjaya Senanayake, David Sholl, William Tarpeh, Francesca Maria Toma, Dionisios Vlachos, Bryan Vogt, Jenny Yang, Elke Arenholz, Brett Helms, Wenyu Huang, James Jordahl, Canan Karakaya, Kourosh Kian, Jotheeswari Kothandaraman, Johannes Lercher, Ping Liu, Deepika Malhotra, Karl Mueller, Casey O'Brien, Robert Palomino, Long Qi, Jose Rodriguez, Roger Rousseau, Jake Russell, Michele Sarazen, Emily Smith, Michaela Burke Stevens, Yogesh Surendranath, Christopher Tassone, Ba Tran, William Tumas, and Krista Walton, "A US Perspective on Closing the Carbon Cycle to Defossilize Difficult-to-electrify Segments of our Economy. Nat. Rev. Chem. 2024, 8, 376-400. DOI: 10.1038/s41570-024-00587-1
108. Weinstein, Z. B.; Sadow, A. D. Copper(I) Iodide Catalyzed Redistribution of Aromatic Carboxylic Acids. J. Catal. 2024, 433, 115467. DOI: 10.1016/j.jcat.2024.115467
107. Luo, Z.; Li, L.; Nguyen, V. T.; Kanbur, U.; Li, Y.; Zhang, J.; Nie, R.; Biswas, A.; Bud’ko, S. L.; Oh, J.; Zhou, L.; Huang, W.; Sadow, A. D.; Wang, B.; Scott, S. L.; Qi, L.* "Catalytic Hydrogenolysis by Atomically-Dispersed Iron Sites Embedded in Chemically Non-Innocent N-Doped Carbon" J. Am. Chem. Soc. 2024, 146, 8618-8629. DOI: 10.1021/jacs.4c00741
106. Lamb, J. V.; Lee, Y.-H.; Sun, J.; Byron, C.; Uppuluri, R.; Kennedy, R. M.; Meng, C.; Behera, R. K.; Wang, Y.-Y.; Qi, L.; Sadow, A. D.; Huang, W.; Ferrandon, M. S.; Scott, S. L.; Poeppelmeier, K. R.; Abu-Omar, M. M.; Delferro, M. "Supported Platinum Nanoparticles Catalyzed Carbon–Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support Acidity." ACS Appl. Mater. Interfaces 2024, 16, 11361-11376. DOI: 10.1021/acsami.3c15350
105. Kim, C. A.; Sahasrabudhe, C. A.; Wang, Y.-Y.; Yappert, R.; Heyden, A.; Huang, W.; Sadow, A. D.; Peters, B. "Population Balance Equations for Reactive Separation in Polymer Upcycling". Langmuir 2024, 40, 4096-4107. DOI: 10.1021/acs.langmuir.3c03004
104. Wang, Y.-Y.; Tennakoon, A.; Wu, X.; Sahasrabudhe, C.; Qi, L.; Peters, B. G.; Sadow, A. D.; Huang, W. "Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation" ACS Catal. 2024, 14, 2084-2094. DOI: 10.1021/acscatal.3c04987
2023
103. Meirow, M.; Tennakoon, A.; Wu, X.; Willmon, J.; Howell, D.; Huang, W.; Sadow, A. D.; Luijten, E. "Influence of Pore Length on Hydrogenolysis of Polyolefins within a Mesoporous Support Architecture" J. Phys. Chem. C., 2023, 127, 23805-23813. DOI: 10.1021/acs.jpcc.3c04300
102. Tennakoon, A.; Wu, X.; Meirow, M.; Howell, D.; Willmon, J.; Yu, J.; Lamb, J. V.; Delferro, M.; Luijten, E.; Huang, W.;* Sadow A. D.* "Two Mesoporous Domains Are Better than One for Catalytic Deconstruction of Polyolefins" J. Am. Chem. Soc. 2023, 145, 17936-17944. DOI: 10.1021/jacs.3c05447
101. Chu, Y.-Y.; Alejo, A. G.; Bud'ko, S. L.; Boteju, K.; Patnaik, S.; Ellern, A.; García, M. P.; Sadow, A. D. "Structure and Magnetic Properties of Homoleptic Trivalent Tris(alkyl)lanthanides" Inorg. Chem., 2023, 62, 11751-11760. DOI: 10.1021/acs.inorgchem.3c00435
100. Zhao, T. Y.; Meirow, M.; Tennakoon, A.; Wu, X.; Paterson, A. L.; Qi, L.; LaPointe, A. M.; Lamb, J. V.; Kobayashi, T.; Delferro, M.; Sadow, A. D.; Huang, W.; Luijten, E.; Perras, F. A., "Mechanistic Insights into Processive Polyethylene Hydrogenolysis through In Situ NMR" Macromolecules 2023, 56, 4287-4295. DOI: acs.macromol.3c00474
99. Chen, S.; Tennakoon, A.; You, K.-E.; Paterson, A. L.; Yappert, R.; Alayoglu, S.; Fang, L.; Wu, X.; Zhao, T. Y.; Lapak, M. P.; Saravanan, M.; Hackler, R. A.; Wang, Y.-Y.; Qi, L.; Delferro, M.; Li, T.; Lee, B.; Peters, B. Poeppelmeier, K. R.; Ammal, S. C.; Bowers, C. R.; Perras, F. A.; Heyden, A.; Sadow, A. D.; Huang, W. "Ultrasmall Amorphous Zirconia Nanoparticles Catalyze Carbon-Carbon Bond Hydrogenolysis" Nat. Catal. 2023, 6, 161-173. DOI: 10.1038/s41929-023-00910-x
98. Kanbur, U.; Paterson, A. L.; Rodriguez, J.; Kocen, A. L.; Yappert, R.; Hackler, R. A.; Wang, Y.-Y.; Peters, B.; Delferro, M.; LaPointe, A. M.; Coates, G. W.; Perras, F. A.; Sadow, A. D.* "Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane" J. Am. Chem. Soc. 2023, 145, 2901-2910. "Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane" J. Am. Chem. Soc. 2023, 145, 2901-2910. DOI: 10.1021/jacs.2c11056
97. McCullough, K. E.; Peczak, I. L.; Kennedy, R.; Wang, Y.-Y.; Lin, J.; Wu, X.; Paterson, A. L.; Perras, F. A.; Hall, J.; Kropf, A. J.; Hackler, R. A.; Shin, Y.; Niklas, J.; Poluektov, O. G.; Wen, J.; Huang, W.; Sadow, A. D.; Poeppelmeier, K. R.; Delferro, M.; Ferrandon, M. S. "Synthesis of Platinum Nanoparticles on Strontium Titanate Nanocuboids via Surface Organometallic Grafting for the Catalytic Hydrogenolysis of Plastic Waste" J. Mater. Chem. A 2023, 11, 1216-1231. DOI:10.1039/D2TA08133D
2022
96. Dorn, R. W.; Paterson, A. L.; Hung, I.; Gor’kov, P. L.; Thompson, A. J.; Sadow, A. D.; Gan, Z.; Rossini, A. J. Dipolar Heteronuclear Correlation Solid-State NMR Experiments between Half-Integer Quadrupolar Nuclei: The Case of 11B–17O. J. Phys. Chem. C 2022, 126, 11652-11666. DOI: 10.1021/acs.jpcc.2c02737
95. Hackler, R.; Lamb, J.; Peczak, I.; Kennedy, R.; Kanbur, U.; LaPointe, A.; Poeppelmeier, K. R.; Sadow, A. D.; Delferro, M. "The Effect of the Macro- and Microstructure on Catalytic Hydrogenolysis of Polyolefins" Macromolecules, 2022, 55, 6801-6810. DOI: 0.1021/acs.macromol.2c00805
94. Wu, X.; Tennakoon, A.; Yappert, R.; Esveld, M.; Ferrandon, M. S.; Hackler, R. A.; LaPointe, A. M.; Heyden, A.; Delferro, M.; Peters, B.; Sadow, A. D.; Huang, W., Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins. J. Am. Chem. Soc. 2022, 144, 5323-5334. DOI:10.1021/jacs.1c11694
93. Li, Y.; Kanbur, U.; Cui, J.; Wang, G.; Kobayashi, T.; Sadow, A. D.; Qi, L. "Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores" Angew. Chem. Int. Ed. 2022, 61, e202117394. DOI:10.1002/anie.202117394
92. Chu, Y.-Y.; Lolinco, A.; Eedugurala, N.; Ellern, A.; Windus, T. W.; Sadow, A. D. "Reversible Ligand Protonation in Non-innocent Constrained-Geometry-like Group 4 Complexes" Organometallics, 2022, 41, 141-154. DOI:10.1021/acs.organomet.1c00612
91. Chatterjee, P.; Wang, H.; Manzano, J. S.; Kanbur, U.; Sadow, A. D.; Slowing, I. I.*, Surface ligands enhance the catalytic activity of supported Au nanoparticles for the aerobic α-oxidation of amines to amides. Catal. Sci. Technol. 2022, 12, 1922-1933. DOI:10.1039/D1CY02121D
90. Perras, F. A.;* Kanbur, U.; Paterson, A. L.; Chatterjee, P.; Slowing, I. I. Sadow, A. D. "Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up" Inorg. Chem. 2022, 61, 1067-1078. DOI:10.1021/acs.inorgchem.1c03200
89. Basemann, K.; Schmidt, B. M.; Sadow, A. D. "Substituent-enhanced Intermolecular Catalytic Ene-yne Metathesis for Efficient 1,3-Diene Synthesis" ACS Catal. 2022, 12, 226-235. DOI:10.1021/acscatal.1c04074
2021
88. Hackler, R. A;. Vyavhare, K.; Kennedy, R. M.; Celik, G.; Kanbur, U.; Griffin, P. J.; Sadow, A. D.; Zang, G.; Elgowainy, A.; Sun, P. Poeppelmeier, K. R.; Erdemir, A.; Delferro, M.*, “Synthetic Lubricants Derived from Plastic Waste and their Tribological Performance.” ChemSusChem 2021, 14, 4181-4189. DOI:10.1002/cssc.202100912
87. Patnaik, S.; Kanbur, U.; Ellern, A.; Sadow, A. D., “Hydrosilane σ-Adduct Intermediates in Mechanistically Rich Zinc-Catalyzed Cross-Dehydrocoupling of Silanes and Alcohols.” Chem. Eur. J. 2021, 27, 10428-10436. DOI:10.1002/chem.202101146
86. Kanbur, U.; Zang, G.; Paterson, A. L.; Chatterjee, P.; Hackler, R. A.; Delferro, M.; Slowing, I. I.; Perras, F. A.; Sun, P.; Sadow A. D., “Catalytic Carbon-Carbon Bond Cleavage and Carbon-Element Bond Formation Gives New Life for Polyolefins as Biodegradable Surfactants.” Chem 2021, 7, 1347-1362. DOI:10.1016/j.chempr.2021.03.007
85. Boteju, K.; Venkatesh, A.; Wan, S.; Ellern, A.; Rossini, A. J.; Sadow, A. D. "Ancillary Steric Effects on the Activation of SiH Bonds in Arylsilazido Rare Earth Compounds" Organometallics, 2021, 40, 1654-1669. DOI:10.1021/acs.organomet.1c00162
84. Eedugurala, N.; Wang, Z.; Kanbur, U.; Ellern, A.; Pruski, M.; Sadow, A. D., “Synthesis and Characterization of Tris(oxazolinyl)borato Copper(II) and Copper(I) Complexes.” Helv. Chim. Acta 2021, 104, e2000209. DOI:10.1002/hlca.202000209
83. Paterson, A. L.; Liu, D.-J.; Kanbur, U.; Sadow, A. D.; Perras, F. A.*, “Observing the three-dimensional dynamics of supported metal complexes.” Inorg. Chem. Front. 2021, 3, 893-901. DOI:10.1039/D0QI01241F
2020
82. Tennakoon, A.; Wu, X.; Paterson, A. L.; Patnaik, S.; Pei, Y.; LaPointe, A. M.; Ammal, S. C.; Hackler, R. A.; Heyden, A.; Slowing, I. I.; Coates, G. W.; Delferro, M.; Peters, B.; Huang, W.; Sadow, A. D.; Perras, F. A., “Catalytic Upcycling of High-Density Polyethylene Via a Processive Mechanism.” Nature Catalysis 2020, 3, 893-901. DOI:10.1038/s41929-020-00519-4
81. Zhou, H.; Wang, H.; Perras, F. A.; Naik, P.; Pruski, M.; Sadow, A. D.; Slowing, I. I., “Two-step conversion of Kraft lignin to nylon precursors under mild conditions.” Green Chem. 2020, 22, 4676-4682. DOI:10.1039/D0GC01220C
80. Luo, Z.; Nie, R.; Nguyen, V. T.; Biswas, A.; Behera, R. K.; Wu, X.; Kobayashi, T.; Sadow, A.; Wang, B.; Huang, W.; Qi, L.*, “Transition metal-like carbocatalyst.” Nature Communications 2020, 11, 4091. DOI:10.1038/s41467-020-17909-8
79. Zhou, H.; Wang, H.; Sadow, A. D.; Slowing, I. I., “Toward Hydrogen Economy: Selective Guaiacol Hydrogenolysis under Ambient Hydrogen Pressure.” Applied Catalysis B: Environmental 2020, 270, 118890-118899. DOI:10.1016/j.apcatb.2020.118890
78. Sadow, A. D., “Alkali and Alkaline Earth Element-Catalyzed Hydroboration Reactions.” In Early Main Group Metal Catalysis 2020, pp. 201-224. DOI:10.1002/9783527818020.ch8
77. Kanbur, U.; Sadow, A. D., “Rare Earth Catalyzed C–H Bond Alumination of Terminal Alkynes.” Chem. Eur. J. 2020, 26, 5479-5493. DOI:10.1002/chem.202000325
76. Wang, Z.; Patnaik, S.; Eedugurala, N.; Manzano, J. S.; Slowing, I. I.; Kobayashi, T.; Sadow, A. D.; Pruski, M., “Silica-supported Organolanthanum Catalysts for C–O Bond Cleavage in Epoxides.” J. Am. Chem. Soc. 2020, 142, 2935-2947. DOI:10.1021/jacs.9b11606
2019
75. Celik, G.; Kennedy, R. M.; Hackler, R. A.; Ferrandon, M.; Tennakoon, A.; Patnaik, S.; LaPointe, A. M.; Ammal, S. C.; Heyden, A.; Perras, F. A.; Pruski, M.; Scott, S. L.; Poeppelmeier, K. R.; Sadow, A. D.; Delferro, M., “Upcycling Single-Use Polyethylene into High-Quality Liquid Products.” ACS Central Science 2019, 5, 1795-1803. DOI:10.1021/acscentsci.9b00722
74. Reinig, R. R.; Ellern, A.; Sadow, A. D., “Heteroleptic Four-Coordinate Tris(oxazolinyl)borato Iron(II) Compounds.” Inorg. Chem. 2019, 58, 6044-6051. DOI:10.1021/acs.inorgchem.9b00359
73. Biswas, A.; Ellern, A.; Sadow, A. D. “CO Displacement in an Oxidative Addition of Primary Silanes to Rhodium(I)” Inorg. Chem. 2019, 58, 3815-3824. DOI:10.1021/acs.inorgchem.8b03425
72. Patnaik, S; Sadow, A. D. “Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage” Angew. Chem. Int. Ed. 2019, 58, 2505-2509. DOI:10.1002/anie.201813305
71. Schmidt, B. S.; Pindwal, A.; Venkatesh, A.; Ellern, A.; Rossini, A. R.; Sadow, A. D. “Zwitterionic Trivalent (Alkyl)Lanthanoid Complexes in Ziegler-type Butadiene Polymerization” ACS Catal. 2019, 9, 827-838. DOI:10.1021/acscatal.8b04025
2018
70. Duchimaza Heredia, J. J.; Sadow, Aaron D.; Gordon, M. S. “A Quasi-Atomic Analysis of Three-Center Two-Electron Zr–H–Si Interactions” J. Phys. Chem. A 2018, 122, 9653-9669. DOI:10.1021/acs.jpca.8b09530
69. Sadow, A. D.; Kwag, G.; Lee, H.; Pindwal, A.; Schmidt, B.S. “Polymerization catalysts” US Patent No.: 9,856,337 B2. Jan 2, 2018.
68. Schmidt, B. S.; Ho, H-.A.; Basemann, K.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Redox chemistry of bis(oxazolinyl)-cyclopentadienyl and -fluorenyl rhodium and iridium organometallic compounds” Organometallics 2018, 37, 4055-4069. DOI:10.1021/acs.organomet.8b00626
67. Kanbur, U.; Ellern, A.; Sadow, A. D. “A zwitterionic neodymium(III) heterobimetallic catalyst for alkynylaluminum synthesis by alkane elimination” Organometallics 2018, 37, 4409-4414. DOI:10.1021/acs.organomet.8b00374
66. Reinig, R. R.; Fought, E. L.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Cobalt(II) acyl intermediates in carbon-carbon bond formation and oxygenation” Dalton Trans. 2018, 47, 12147-12161. DOI:10.1039/C8DT02661K
65. Boteju, K. C.; Wan, S.; Venkatesh, A.; Ellern, A.; Rossini, A. J.; Sadow, A. D., “Rare earth arylsilazido compounds with inequivalent secondary interactions.” Chem. Commun. 2018, 54, 7318-7321. DOI:10.1039/C8CC03186J
64. Venkatesh, A.; Ryan, M.; Biswas, A.; Boteju, K; Sadow, A. D.; Rossini, A. J., “Enhancing the Sensitivity of Solid-State NMR Experiments with Very Low Gyromagnetic Ratio Nuclei with Fast Magic Angle Spinning and Proton Detection” J. Phys.Chem. A, 2018, 122, 5635-5643. DOI:10.1021/acs.jpca.8b05107
63. Perras, F. A.; Boteju, K. C.; Slowing, I. I.; Sadow, A. D.; Pruski, M., “Direct 17O dynamic nuclear polarization of single-site heterogeneous catalysts.” Chem. Commun., 2018, 54, 3472-3475. DOI:10.1039/C8CC00293B
2017
62. Pindwal, A.; Yan, K.; Patnaik, S.; Schmidt, B. M.; Ellern, A.; Slowing, I. I.; Bae, C.; Sadow, A. D. “Homoleptic Trivalent Tris(Alkyl) Rare Earth Compounds” J. Am. Chem. Soc., 2017, 139, 16862-16874. DOI:10.1021/jacs.7b09521
61. Reinig, R. R.; Fought, E. L.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl complex” Chem. Commun., 2017, 53, 11020-11023. DOI:10.1039/C7CC06339C
60. Manzano, J. S.; Weinstein, Z. B.; Sadow, A. D.; Slowing, I. I. “Direct 3D Printing of Catalytically Active Structures” ACS Catalysis, 2017, 7, 7567-7577. DOI:10.1021/acscatal.7b02111
59. Lampland, N. L.; Pindwal, A.; Yan, K.; Ellern, A.; Sadow, A. D. “Rare Earth and Main Group Metal Poly(hydrosilyl) Compounds” Organometallics, 2017, 36, 4546-4557. DOI:10.1021/acs.organomet.7b00383
58. Kobayashi, T.; Perras, F. A.; Chaudhary, U.; Slowing, I. I.; Huang, W.; Sadow, A. D.; Pruski, M. “Improved strategies for DNP-enhanced 2D 1H-X heteronuclear correlation spectroscopy of surfaces” Solid State Nuclear Magnetic Resonance, 2017, 87(c), 38-44. DOI:10.1016/j.ssnmr.2017.08.002
57. Perras, F.; Sadow, A. D.; Pruski, M.; “In Silico Design of DNP Polarizing Agents: Can Current Dinitroxides be Improved?” ChemPhysChem, 2017, 18, 2279-2287. DOI:10.1002/cphc.201700299
56. Eedugurala, N.; Wang, Z.; Yan, K.; Boteju, K. C.; Chaudhary, U.; Kobayashi, T.; Ellern, A.; Slowing, I. I.; Pruski, M.; Sadow, A. D. “β-SiH-Containing Tris(silazido) Rare-Earth Complexes as Homogeneous and Grafted Single-Site Catalyst Precursors for Hydroamination” Organometallics, 2017, 36, 1142-1153. DOI:10.1021/acs.organomet.6b00956
55. Boteju, K. C.; Ellern, A.; Sadow, A. D. “Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand” Chem. Commun. 2017, 53, 716-719. DOI:10.1039/C6CC09304C
54. Pindwal, A.; Patnaik, S.; Everett, W. C.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Cerium-catalyzed Hydrosilylation of Acrylates to α-Silyl Esters” Angew. Chem. Int. Ed. 2017, 56, 628-631. DOI:10.1002/anie.201610263
2016
53. García, A.; Wang, J.; Windus, T. L.; Sadow, A. D.; Evans, J. W., “Catalytic conversion reactions in nanoporous systems with concentration-dependent selectivity: Statistical mechanical modeling” Phys. Rev. E, 2016, 93, 052137. DOI:10.1103/PhysRevE.93.052137
52. Pindwal, A.; Ellern, A.; Sadow, A. D. “Homoleptic Divalent Dialkyl Lanthanide-Catalyzed Cross-Dehydrocoupling of Silanes and Amines” Organometallics, 2016, 35, 1674-1683. DOI:10.1021/acs.organomet.6b00138
51. Reinig, R. R.; Mukherjee, D.; Weinstein, Z. B.; Xie, W.; Albright, T.; Baird, B.; Gray, T. S.; Ellern, A.; Miller, G. J.; Winter, A. H.; Bud’ko, S. L.; Sadow, A. D.* “Synthesis and Oxidation Catalysis of Tris(oxazolinyl)borate Cobalt(II) Scorpionate” Eur. J. Inorg. Chem. 2016, 2486-2494. DOI:10.1002/ejic.201600237
50. Perras, F. A.; Reinig, R. R.; Slowing, I. I.; Sadow, A. D.; Pruski, M., Effects of biradical deuteration on the performance of DNP: towards better performing polarizing agents. Phys. Chem. Chem. Phys. 2016, 18, 65-69. DOI:10.1039/c5cp06505d
2015
49. Zhang, L.; Wu, Z.; Nelson, N. C.; Sadow, A. D.; Slowing, I. I.; Overbury, S. H.,* “Role Of CO2 As a Soft Oxidant For Dehydrogenation of Ethylbenzene to Styrene over a High-Surface-Area Ceria Catalyst.” ACS Catal. 2015, 5, 6426-6435. DOI:10.1021/acscatal.5b01519
48. Eedugurala, N.; Hovey, M.; Ho, H.-A.; Jana, B.; Lampland, N. L.; Ellern, A.; Sadow, A. D. “Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations” Organometallics, 2015, 34, 5566-5575. DOI:10.1021/acs.organomet.5b00771
47. Eedugurala, N.; Wang, Z.; Chaudhary, U.; Nelson, N. C.; Kandel, K.; Kobayashi, T.; Slowing, I. I.; Pruski, M.; Sadow, A. D. “Mesoporous Silica-supported Amidozirconium-Catalyzed Carbonyl Hydroboration.” ACS Catal. 2015, 5, 7399-7414. DOI:10.1021/acscatal.5b01671
46. Kobayashi, T.; Perras, F. A.; Slowing, I. I.; Sadow, A. D.; Pruski, M.,* Dynamic Nuclear Polarization Solid-State NMR in Heterogeneous Catalysis Research. ACS Catal. 2015, 5, 7055-7062. DOI:10.1021/acscatal.5b02039
45. Lampland, N. L.; Pindwal, A.; Neal, S. R.; Schauderaff, S.; Ellern, A.; Sadow, A. D. “Hydrosilylation of α,β-Unsaturated Esters Catalyzed by a Magnesium Hydridoborate.” Chem. Sci. 2015, 6, 6901-6907. DOI:10.1039/c5sc02435h
44. Xu, S.; Boschen, J. S.; Kobayashi, T.; Pruski, M.; Windus, T. L.; Sadow, A. D. “Partial Deoxygenation of Esters Catalyzed by an Oxazoline-coordinated Rhodium Silylene.” Dalton Trans. 2015, 44, 15897-15904. DOI:10.1039/c5dt02844b
43. Lampland, N. L.; Zhu, J.; Ellern, A.; Sadow, A. D. “Piano-stool Lutetium Amido and Imido Compounds Supported by a Bis(oxazoline)cyclopentadienyl Ligand.” Inorg. Chem. 2015, 54, 6938-6946. DOI:10.1021/acs.inorgchem.5b00927
42. Lampland, N. L.; Hovey, M. L.; Mukherjee, D.; Sadow, A. D. “Magnesium-catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines.” ACS Catal. 2015, 5, 4219-4226. DOI:10.1021/acscatal.5b01038
41. Xu, S.; Magoon, Y.; Reinig, R. R.; Schmidt, B. M.; Ellern, A.; Sadow, A. D. “Organometallic Complexes of Bulky, Optically Active C3-Symmetric Tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*).” Organometallics, 2015, 34, 3508-3519. DOI:10.1021/acs.organomet.5b00225
40. Nelson, N.; Manzano, J.; Sadow, A.; Overbury, S.; Slowing, I. I.* “Selective Hydrogenation of Phenol Catalyzed by Palladium on High Surface Ceria at Room Temperature and Ambient Pressure.” ACS Catal. 2015, 6, 2051-2061. DOI:10.1021/cs502000j
39. Manna, K.; Eedugurala, N.; Sadow, A. D. “Zirconium-catalyzed Desymmetrization of Aminodialkenes and Aminodialkynes through Enantioselective Hydroamination.” J. Am. Chem. Soc. 2015, 137, 425-435. DOI:10.1021/ja511250m
2014
38. Xu, S.; Manna, K.; Ellern, A.; Sadow, A. D. “Mixed N-Heterocyclic Carbene-bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions.” Organometallics, 2014, 33, 6840-6860. DOI:10.1021/om500891h
37. Lampland, N. L.; Ellern, A.; Sadow, A. D. “β-SiH Rich Zinc Silyl Compounds: Reductive Elimination and β-SiH Abstraction.” Inorg. Chim. Acta, 2014, 422, 134-140. DOI:10.1016/j.ica.2014.07.003
36. Xu, S.; Everett, W. C.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Oxygen Insertion Reactions of Mixed N-Heterocyclic Carbene-Oxazolinylborato Zinc Alkyl Complexes.” Dalton Trans. 2014, 43, 14368-14376. DOI:10.1039/C4DT01011F
35. Yan, K.; Pindwal, A.; Ellern, A. Sadow, A. D. “Direct Hydrosilylation by a Zirconacycle with β-Hydrogen.” Dalton Trans. 2014, 43, 8644-8653. DOI:10.1039/C4DT00658E
34. Mukherjee, D.; Ellern, A.; Sadow, A. D. “Magnesium-catalyzed Hydroboration of Esters Via a New Zwitterionic Mechanism.” Chem. Sci. 2014, 5, 959-964. DOI:10.1039/C3SC52793J
2013
33. Yan, K.; Duchimaza Heredia, J. J.; Ellern, A.; Gordon, M. S.; Sadow, A. D. “Lewis Base Mediated β-Elimination and Lewis Acid Mediated Insertion Reactions of Disilazido Zirconium Compounds.” J. Am. Chem. Soc. 2013, 135, 15225-15227. DOI:10.1021/ja407950e
32. Yan, K.; Upton, B. M.; Zhu, J.; Ellern, A.; Sadow, A. D. “Nucleophilicity of Neutral Versus Cationic Magnesium Silyl Compounds.” Organometallics, 2013, 32, 6834–6843. DOI:10.1021/om400447q
31. Manna, K.; Everett, W. S.; Schoendorff, G.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Highly Enantioselective Zirconium Catalyzed Cyclization of Aminoalkenes.” J. Am. Chem. Soc. 2013, 135, 7235-7250. DOI:10.1021/ja4000189
30. Sadow A.D. “Stereoselective C-N Bond Formation by Hydroamination of Olefins, Alkynes, Allenes, and Dienes.” J. Reedijk and K. Poeppelmeier, Eds. Comprehensive Inorganic Chemistry II, Vol 6. Oxford: Elsevier; 2013. p. 487-520.
29. Yan, K.; Sadow, A. D. “C-H Bond Activation by a Zirconacycle.” Chem. Commun. 2013, 49, 3212-3214. DOI:10.1039/c3cc40774h
28. Yan, K.; Schoendorff, G.; Upton, B. M.; Ellern, A.; Windus, T.; Sadow, A. D. “Intermolecular β-Hydrogen Abstractions in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl Compounds.” Organometallics, 2013, 32, 1300-1316. DOI:10.1021/om3010299
27. Mukherjee, D.; Lampland, N. L.; Yan, K.; Dunne, J. F.; Ellern, A.; Sadow, A. D. “Divergent Reaction Pathways of Tris(oxazolinyl)borato Zinc and Magnesium Silyl Compounds.” Chem. Commun. 2013, 49, 4334-4336. DOI:10.1039/C2CC36953B
2012
26. Jana, B.; Hovey, M.; Ellern, A.; Pestovsky, O.; Sadow, A. D.; Bakac, A. “Unusual Structural Motif in a Zwitterionic Fe(II) Complex of a Tetradentate Phosphine.” Dalton Trans. 2012, 41, 12781-12785. DOI:10.1039/C2DT31437A
25. Ho, H.-A.; Manna, K.; Sadow, A. D. “Acceptorless Photolytic Dehydrogenation for Alcohol Decarbonylation and Imine Synthesis.” Angew. Chem., Int. Ed. 2012, 51, 8607-8610. DOI:10.1002/anie.201203556
24. Mukherjee, D.; Ellern, A.; Sadow, A. D. “Remarkably Robust Monomeric Alkylperoxyzinc Compounds from Tris(oxazolinyl)boratozinc Alkyls and O2.” J. Am. Chem. Soc. 2012, 134, 13018-13026. DOI:10.1021/ja303440n
23. Yan, K.; Ellern, A.; Sadow, A. D. “Non-classical β-Hydrogen Eliminations from Hydrosilazido Zirconium Compounds via Direct Hydrogen Transfer.” J. Am. Chem. Soc. 2012, 134, 9154-9156. DOI:10.1021/ja302226c
22. Zhu, J.; Mukherjee, D.; Sadow, A. D. “Abstractions of β-Hydrogen vs. Alkyl Groups in Reactions of Dialkylzinc Compounds and Bis(oxazolinyl)borane.” Chem. Commun. 2012, 48, 464-466. DOI:10.1039/C1CC16113J
2011
21. Manna, K.; Kruse, M. L.; Sadow, A. D. “Concerted C-N/C-H Bond Formation in Highly Enantioselective Yttrium(III)-Catalyzed Hydroamination.” ACS Catal. 2011, 1, 1637-1642. DOI:10.1021/cs200511z
20. Chintareddy, V. R.; Ho, H.-A. Sadow, A. D.; Verkade,* J. G. “Polymer-mounted N3=P(MeNCH2CH2)3N: A Green, Efficient, and Recyclable Catalyst for Room-temperature Transesterifications and Amidations of Unactivated Esters.” Tetrahedron Lett. 2011, 52, 6523-6529. DOI:10.1016/j.tetlet.2011.09.102
19. Dunne, J. F.; Neal, S. R.; Engelkemier, J.; Ellern, A.; Sadow, A. D. “Tris(oxazolinyl)boratomagnesium-catalyzed Cross-dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia.” J. Am. Chem. Soc. 2011, 133, 16782-16785. DOI:10.1021/ja207641b
18. Wu, K.; Mukherjee, D.; Ellern, A.; Sadow, A. D.; Geiger, W. E. “Anodic Electrochemical Behavior of New Mn and Re Tricarbonyl Complexes of Tris(oxazolinyl)phenyl borate Ligands: Comparison to Analogous Tris(pyrazolyl) borate Complexes.” New J. of Chem. 2011, 35, 2169-2178. DOI:10.1039/C1NJ20222G
17. Mukherjee, D.; Thompson, R.; Ellern, A. Sadow, A. D. “A Coordinatively Saturated Tris(oxazolinyl)borato Zinc Hydride-Catalyzed Cross Dehydrocoupling of Silanes and Alcohols.” ACS Catal. 2011, 1, 698-702. DOI:10.1021/cs2001016
16. Ho, H.-A.; Gray, T. S.; Baird, B.; Ellern, A.; Sadow, A. D. “Allylic C–H Bond Activation and Functionalization Mediated by Tris(oxazolinyl)borato Rhodium(I) and Iridium(I) Compounds.” Dalton Trans. 2011, 40, 6500-6514. DOI:10.1039/C1DT10249D
15. Jana, B.; Ellern, A.; Pestovsky, O. Sadow, A. D. Bakac, A. “Synthesis of Monomeric Fe(II) and Ru(II) Complexes of Tetradentate Phosphines.” Inorg. Chem. 2011, 50, 3010-3016. DOI:10.1021/ic102510c
14. Manna, K.; Xu, S.; Sadow, A. D. “A Highly Enantioselective Zirconium Catalyst for Intramolecular Alkene Hydroamination: Significant Isotope Effects on Rate and Stereoselectivity.” Angew. Chem Int. Ed. 2011, 50, 1865-1868. DOI:10.1002/anie.201006163
13. Neal, S. R.; Ellern, A.; Sadow, A. D. “Optically Active, Bulky Tris(oxazolinyl)borato Magnesium and Calcium Compounds for Asymmetric Hydroamination/Cyclization.” J. Organomet. Chem. 2011, 696, 228-234. DOI:10.1016/j.jorganchem.2010.08.057
2010
12. Dunne, J. F.; Fulton, D. B.; Ellern, A.; Sadow, A. D. “Concerted C–N and C–H Bond Formation in a Magnesium-Catalyzed Hydroamination.” J. Am. Chem. Soc. 2010, 132, 17680-17683. DOI:10.1021/ja108881s
11. Ho, H.-A.; Dunne, J. F.; Ellern, A.; Sadow, A. D. “Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C-X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition.” Organometallics, 2010, 29, 4105-4114. DOI:10.1021/om100515u
10. Mukherjee, D.; Ellern, A. Sadow, A. D. “Conversion of a Zinc Disilazide to a Zinc Hydride Mediated by LiCl.” J. Am. Chem. Soc. 2010, 132, 7582-7583. DOI:10.1021/ja102323g
9. Manna, K.; Ellern, A.; Sadow, A. D. “A Zwitterionic Zirconium Complex that Catalyzes Hydroamination at Room Temperature.” Chem. Commun. 2010, 46, 339-441. DOI:10.1039/B918989K
8. Dunne, J. F.; Manna, K.; Wiench, J. W.; Ellern, A.; Pruski, M.; Sadow, A. D. “Bis(oxazolinyl)phenylborane: A Lewis Acid-containing Ligand for Methide Abstraction-based Coordination to Aluminum(III).” Dalton Trans. 2010, 39, 641-653. DOI:10.1039/B911851A
7. Neal, S. R.; You, J.; Ellern, A.; Sadow, A. D. “Palladium and Rhodium Complexes Containing 1,3-Bis(oxazolinyl)propyl (Probox) Ligands: Macrocycles and Pincer Compounds.” Polyhedron, 2010, 29, 544-554. DOI:10.1016/j.poly.2009.06.072
2009
6. Yan, K.; Upton, B.; Ellern, A.; Sadow, A. D. “Lewis Acid Mediated β-Hydride Abstraction Reactions of Divalent M(C(SiHMe2)3)2THF2 (M = Ca, Yb).” J. Am. Chem. Soc. 2009, 131, 15110-15111. DOI:10.1021/ja9070865
5. Pawlikowski, A. V.; Gray, T. S.; Schoendorff, G.; Baird, B.; Ellern, A.; Windus, T. L.; Sadow, A. D. “Structure, Bonding, and Ligand-based Reactions of Zwitterionic Boratoiridium(I) Complexes with Oxazoline-based Scorpionate Ligands.” Inorg. Chim. Acta, 2009, 362, 4517-4525. DOI:10.1016/j.ica.2009.06.017
4. Pawlikowski, A. V.; Ellern, A.; Sadow, A. D. “Ligand Exchange Reactions and Hydroamination with Tris(oxazolinyl)borato Yttrium Compounds.” Inorg. Chem. 2009, 48, 8020-8029. DOI:10.1021/ic900689
3. Yan, K.; Pawlikowski, A. V.; Ebert, C.; Sadow, A. D. “A Tris(alkyl)yttrium Compound Containing Six β-Agostic Si–H Interactions.” Chem. Commun. 2009, 656-658. DOI:10.1039/b818630h
2008
2. Baird, B.; Pawlikowski, A. V.; Su, J.; Wiench, J. W.; Pruski, M.; Sadow, A. D. “Easily-prepared Chiral Scorpionates: Tris(2-oxazolinyl)borate Iridium(I) Compounds and their Interactions with MeOTf.” Inorg. Chem. 2008, 47, 10208-10210. DOI:10.1021/ic801637s
1. Dunne, J. F.; Su, J.; Ellern, A.; Sadow, A. D., “A New Scorpionate Ligand: Tris(4,4-dimethyl-oxazolinyl)borate and Its Zirconium(IV) Complexes.” Organometallics, 2008, 27, 2399-2401. DOI:10.1021/om800252p